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ChemInform Abstract: Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes.

✍ Scribed by Yu Shibata; Ken Tanaka

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
41
Category
Article
ISSN
0931-7597

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The work describes a general direct intermolecular hydroacylation -not reported so far -of 1-alkene with aldehyde using the cocatalyst system of the transition metal complex and 2-amino-3-picoline. Some other metal complexes are also catalytically active. Without the addition of the picoline derivat