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ChemInform Abstract: Solvent-Free Chelation-Assisted Intermolecular Hydroacylation: Effect of Microwave Irradiation in the Synthesis of Ketone from Aldehyde and 1-Alkene by Rh(I) Complex.

✍ Scribed by Chul-Ho Jun; Jong-Hwa Chung; Dae-Yon Lee; Andre Loupy; Saber Chatti

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200139046

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ChemInform Abstract: Chelation-Assisted

ChemInform Abstract: Chelation-Assisted Intermolecular Hydroacylation: Direct Synthesis of Ketone from Aldehyde and 1-Alkene.

✍ C.-H. JUN; H. LEE; J.-B. HONG 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

The work describes a general direct intermolecular hydroacylation -not reported so far -of 1-alkene with aldehyde using the cocatalyst system of the transition metal complex and 2-amino-3-picoline. Some other metal complexes are also catalytically active. Without the addition of the picoline derivat