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ChemInform Abstract: Highly Functionalized Bicyclo[2.2.2]octenone-fused [60]Fullerenes from Masked o-Benzoquinones and C60.

✍ Scribed by Chi-Feng Yen; Rama Krishna Peddinti; Chun-Chen Liao

Publisher
John Wiley and Sons
Year
2001
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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## Synthesis of Stable Bromo-Substituted Masked o-Benzoquinones and Their Application to the Synthesis of Bicyclo[2.2.2]octenones. -Oxidation of the brominated phenol (II) in the presence of dienophiles generates adducts (V) via a masked o-benzoquinone. Debromonation of the adducts gives the bicy