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ChemInform Abstract: Highly Enantioselective or Not? — Chiral Monodentate Monophosphorus Ligands in the Asymmetric Hydrogenation.

✍ Scribed by Igor V. Komarov; Armin Boerner

Publisher: John Wiley and Sons
Year: 2010
Weight: 24 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200124261

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Mild Conditions. -A new chiral bis-phosphine ligand with a paracyclophane backbone is prepared and used as ligand in Rh-catalyzed hydrogenations of dehydroamino acid esters such as (I) with high enantioselectivity. -(PYE, P.