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ChemInform Abstract: A New Planar Chiral Bisphosphine Ligand for Asymmetric Catalysis: Highly Enantioselective Hydrogenations under Mild Conditions.

✍ Scribed by P. J. PYE; K. ROSSEN; R. A. REAMER; N. N. TSOU; R. P. VOLANTE; P. J. REIDER

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199741051

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✦ Synopsis

Mild Conditions. -A new chiral bis-phosphine ligand with a paracyclophane backbone is prepared and used as ligand in Rh-catalyzed hydrogenations of dehydroamino acid esters such as (I) with high enantioselectivity. -(PYE, P.

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