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ChemInform Abstract: Highly Enantioselective Hydrogenation of β-Acyloxy and β-Acylamino α,β-Unsaturated Phosphonates Catalyzed by Rhodium Phosphane-Phosphite Complexes.

✍ Scribed by M. Angeles Chavez; Sergio Vargas; Andres Suarez; Eleuterio Alvarez; Antonio Pizzano

Publisher
John Wiley and Sons
Year
2012
Weight
52 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The Rh complex (RPO) efficiently promotes the asymmetric hydrogenation of title phosphonates giving synthetically and biologically important β‐functionalized phosphonates in high optical purity.

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