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Enantioselective Hydrogenation of β-Acylamino Acrylates Catalyzed by Rhodium(I)-Monophosphite Complexes

✍ Scribed by Thomas Jerphagnon; Jean-Luc Renaud; Patrice Demonchaux; Amadéo Ferreira; Christian Bruneau


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
66 KB
Volume
346
Category
Article
ISSN
1615-4150

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The reaction of [Ir(m-Cl)(COD)] 2 with various fluorous derivatives of triphenylphosphane containing a para-, meta-, or ortho-(1H,1H-perfluoroalkoxy)-substituted fluorous phosphane P(C 6 H 4 -ORf) 3 (Rf CH 2 C 7 F 15 , CH 2 CH 2 CH 2 C 8 F 17 ) and CO (1 atm) gives the corresponding trans-[Ir(m-Cl)(