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ChemInform Abstract: Highly Enantioselective Hydrogenation of Aryl Vinyl Ketones to Allylic Alcohols Catalyzed by the Tol-Binap/Dmapen Ruthenium(II) Complex.

✍ Scribed by Noriyoshi Arai; Keita Azuma; Noriyuki Nii; Takeshi Ohkuma

Publisher
John Wiley and Sons
Year
2009
Weight
44 KB
Volume
40
Category
Article
ISSN
0931-7597

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## Abstract A Ru(II)β€”dichlorobipyridine complex (Ia) efficiently catalyzes the redox isomerization of terminal and internal allylic alcohols to give the corresponding ketones, e.g. (III), (V) or (VII), in high to excellent conversion.