✦ LIBER ✦
ChemInform Abstract: Highly Enantioselective Alkynylation of Trifluoropyruvate with Alkynylsilanes Catalyzed by the BINAP—Pd Complex: Access to α-Trifluoromethyl-Substituted Tertiary Alcohols.
✍ Scribed by Kohsuke Aikawa; Yuta Hioki; Koichi Mikami
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 77 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
The process is highly successful including the addition of polyynes such as (VI) and (VIII) to trifluoropyruvate (II).