Efficient, Ecologically Benign, Aerobic Oxidation of Alcohols. -Under optimized conditions, using oxygen as stoichiometric oxidant and catalytic amounts of CuCl(phen) and either hydrazines or azo compounds, various alcohols are oxidized to the corresponding aldehydes or ketones in good yields. The
ChemInform Abstract: Highly Efficient, Organocatalytic Aerobic Alcohol Oxidation.
โ Scribed by Masatoshi Shibuya; Yuji Osada; Yusuke Sasano; Masaki Tomizawa; Yoshiharu Iwabuchi
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 43 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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Oxidation ## Oxidation O 0212 Transition-Metal-Free: A Highly Efficient Catalytic Aerobic Alcohol Oxidation Process. -The title reaction is carried out under air using a catalyst consisting of TEMPO, Br 2 and, NaNO 2 . Under optimal reaction conditions, a wide range of alcohols can be converted