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ChemInform Abstract: Highly Active and Enantioselective Copper-Catalyzed Conjugate Addition of Diethylzinc to Cyclohexenone Using Sugar Derivative Diphosphites.

✍ Scribed by Oscar Pamies; Montserrat Dieguez; Gemma Net; Aurora Ruiz; Carmen Claver

Publisher
John Wiley and Sons
Year
2001
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective Co
ChemInform Abstract: Enantioselective Conjugate Addition of Diethylzinc to Cyclohexenone Catalyzed by a Chiral Aminophosphineβ€”Copper(II) Triflate.
✍ Toshiyuki Mori; Kyoko Kosaka; Yuichi Nakagawa; Yasuo Nagaoka; Kiyoshi Tomioka πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 2 views

Enantioselective Conjugate Addition of Diethylzinc to Cyclohexenone Catalyzed by a Chiral Aminophosphine-Copper(II) Triflate. -The reaction allows the formation of chiral cyclohexanones (III) in up to 70% e.e.