✦ LIBER ✦

ChemInform Abstract: Enantioselective Conjugate Addition of Diethylzinc to Cyclohexenone Catalyzed by a Chiral Aminophosphine—Copper(II) Triflate.

✍ Scribed by Toshiyuki Mori; Kyoko Kosaka; Yuichi Nakagawa; Yasuo Nagaoka; Kiyoshi Tomioka

No coin nor oath required. For personal study only.

✦ Synopsis

Enantioselective Conjugate Addition of Diethylzinc to Cyclohexenone Catalyzed by a Chiral Aminophosphine-Copper(II) Triflate.

-The reaction allows the formation of chiral cyclohexanones (III) in up to 70% e.e.

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