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ChemInform Abstract: Enantioselective Conjugate Addition of Diethylzinc to Enones Catalyzed by a Copper Complex of Chiral Aryl Diphosphite.

✍ Scribed by Ming Yan; Li-Wei Yang; Kwok-Yin Wong; Albert S. C. Chan

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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Enantioselective Conjugate Addition of Diethylzinc to Cyclohexenone Catalyzed by a Chiral Aminophosphine-Copper(II) Triflate. -The reaction allows the formation of chiral cyclohexanones (III) in up to 70% e.e.