ChemInform Abstract: Gold-Catalyzed Oxidative Cyclizations of 2-Oxiranyl-1-alkynylbenzenes for Diastereoselective Synthesis of Highly Substituted 2-Hydroxyindanones.
β Scribed by Rupsha Chaudhuri; Rai-Shung Liu
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 46 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Gold-Catalyzed Oxidative Cyclizations of 2-Oxiranyl-1-alkynylbenzenes for Diastereoselective Synthesis of Highly Substituted 2-Hydroxyindanones. -It allows a new and diastereoselective access to various 2-hydroxyindanones like (II), (IV), and
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Highly Regioselective Synthesis of Substituted Tetrahydroquinolines by Palladium-Catalyzed Cyclization of Substituted 2-Amidophenylmalonates with 1,4-Diacetoxybut-2-ene. -The regioselectivity depends on the substituent at the amino group. Sulfonamide-type substrates provide 3-vinyl-substituted tetra