ChemInform Abstract: Highly Enantio- and Diastereoselective Synthesis of 2-Substituted 1-Bicyclo[3.1.0]hexanols.
β Scribed by R. MIZOJIRI; H. URABE; F. SATO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of Highly Substituted Bicyclo(3.2.0)heptanones from 3-Homoallylcyclobutenones. A Total Synthesis of (Β±)-Precapnelladiene. -The stereoselective rearrangement of the title cyclobutenones is obtained by heating in xylene and represents a new and general synthetic method for bicycloheptanones