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ChemInform Abstract: Highly Regioselective Synthesis of Substituted Tetrahydroquinolines by Palladium-Catalyzed Cyclization of Substituted 2-Amidophenylmalonates with 1,4-Diacetoxybut-2-ene.

✍ Scribed by Masahiro Yoshida; Yohei Maeyama; Kozo Shishido

Publisher: John Wiley and Sons
Year: 2011
Weight: 31 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201109157

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✦ Synopsis

Highly Regioselective Synthesis of Substituted Tetrahydroquinolines by Palladium-Catalyzed Cyclization of Substituted 2-Amidophenylmalonates with 1,4-Diacetoxybut-2-ene. -The regioselectivity depends on the substituent at the amino group. Sulfonamide-type substrates provide 3-vinyl-substituted tetrahydroquinolines, whereas alkoxycarbonyl compounds furnish 2-vinyl products. -(YOSHIDA*, M.;

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