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ChemInform Abstract: General Synthesis of α-Acetoxy Ethers from Esters by DIBALH Reduction and Acetylation.

✍ Scribed by V. H. DAHANUKAR; S. D. RYCHNOVSKY

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

General Synthesis of α-Acetoxy Ethers from Esters by DIBALH Reduction and Acetylation.

-The mechanism for the formation of title products, e.g. (III), (V), and (VII), is discussed. The α-acetoxy esters are versatile 1,3-diol synthons that can serve as starting material for the synthesis of further products via carbon-carbon bond formation. -(DAHANUKAR,

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