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ChemInform Abstract: Stereoselective Synthesis of 1,2-Amino Alcohols by Asymmetric Borane Reduction of α-Oxoketoxime Ethers.

✍ Scribed by M. MASUI; T. SHIOIRI


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Syn
✍ M. MASUI; T. SHIOIRI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

Stereoselective Synthesis of Sphinganine by Means of Modified Asymmetric Borane Reduction. -A modified asymmetric borane reduction of the ester (I) and the related silyl ether (V) are described. Thus, reduction of the ester yields mainly the threo compound, whereas the silyl ether affords the desir