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ChemInform Abstract: Stereoselective Synthesis of Sphinganine by Means of Modified Asymmetric Borane Reduction.

✍ Scribed by M. MASUI; T. SHIOIRI

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Stereoselective Synthesis of Sphinganine by Means of Modified Asymmetric Borane Reduction.

-A modified asymmetric borane reduction of the ester (I) and the related silyl ether (V) are described. Thus, reduction of the ester yields mainly the threo compound, whereas the silyl ether affords the desired erythro isomer sphinganine. The products are isolated as N-benzoyl derivatives. -(MASUI, M.;

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