Fourier transform infrared spectroscopy has been used to identify and quantify FC(O)OOC (0)F and COP as products following the self-reaction of FC(O)Os radicals. Fmm the observed product yields, it was determined that the reaction proceeds pro dominately (80%+20%), if not exclusively, via FC(O)O,+FC
ChemInform Abstract: FTIR-Spectroscopic Study of Reactions of FCO and FC(O)OO Radicals in the Presence of O2 and NO2.
β Scribed by G. BEDNAREK; G. A. ARGUEELLO; R. ZELLNER
- Book ID
- 112034878
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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A pulse radiolysis system was used to study the kinetics of the reaction of FC(0)Oz radicals with NOz. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be (5.5 ? 0.6) X 10-l' cm3 molecule-' 5-l a t 296 K and 500-1000 mbar pressure
Based on a n FTIR-product study of the photolysis of mixtures containing Br,-CH3CH0 and Br,-CH3CHO-HCHO in 700 torr of N,, the rate constant for the reaction Br + CHBCHO + HBr + CH3C0 was determined to be 3.7 x lo-', cm3 molecule-' sf'. In addition, the selective photochemical generation of Br at A