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ChemInform Abstract: Formation and Synthetic Use of Oxygen-Centered Radicals with ( Diacetoxyiodo)arenes.

✍ Scribed by H. TOGO; T. MURAKI; Y. HOSHINA; K. YAMAGUCHI; M. YOKOYAMA


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Formation and Synthetic Use of Oxygen-Centered Radicals with ( Diacetoxyiodo)arenes. -The usefulness of the photochemical cyclization of aromatic carboxylic acids and alcohols to their corresponding lactones and cyclic ethers is presented. The advantage of this methodology is the lower toxicity of the used iodo-compounds compared to lead tetraacetate used in previous methods. -(TOGO, H.


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