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ChemInform Abstract: Facile Total Synthesis of the (-)-Heliconol A.

✍ Scribed by Weiguo Quan; Binxun Yu; Jiyong Zhang; Qiren Liang; Xuegong She; Xinfu Pan

Publisher
John Wiley and Sons
Year
2008
Weight
17 KB
Volume
39
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Facile Total Synthesis of (Β±)-Adalinine. -Allylation of cyclic N-acyl-N,O-acetals using a combination of allylsilane and Lewis acid provides a useful construction of 6,6-disubstituted 2-piperidones. Compound (VIII) can be readily converted to the ladybird alkaloid (X) mentioned in the title. -(YAMA