A Facile Total Synthesis of Rutaecarpine.
β Scribed by Subhash P. Chavan; R. Sivappa
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 78 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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Facile Total Synthesis of (Β±)-Adalinine. -Allylation of cyclic N-acyl-N,O-acetals using a combination of allylsilane and Lewis acid provides a useful construction of 6,6-disubstituted 2-piperidones. Compound (VIII) can be readily converted to the ladybird alkaloid (X) mentioned in the title. -(YAMA