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ChemInform Abstract: Expeditious Synthesis of Helianane (IV) and C-10 Halogenated Heliananes (V) Employing Ring-Closing Metathesis.

✍ Scribed by Subir Sabui; Subrata Ghosh; Debayan Sarkar; Ramanathapuram V. Venkateswaran

Publisher
John Wiley and Sons
Year
2009
Weight
28 KB
Volume
40
Category
Article
ISSN
0931-7597

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Expeditious synthesis of helianane and C
Expeditious synthesis of helianane and C-10 halogenated heliananes employing ring-closing metathesis
✍ Subir Sabui; Subrata Ghosh; Debayan Sarkar; Ramanathapuram V. Venkateswaran πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 198 KB

An expeditious synthesis of the marine sesquiterpene helianane enclosing an unusual benzoxocane ring system is described employing ring-closing metathesis as the key step. Helianane has been further converted to the naturally occurring C-10 bromo and chloro derivatives.