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ChemInform Abstract: Synthesis of Highly Functionalized Carbohydrate-Derived Spiroacetals by Ring-Closing Metathesis and Pauson—Khand Reaction of Ketoglycosidic Enynes.

✍ Scribed by Michiel A. Leeuwenburgh; Chantal C. M. Appeldoorn; Peter A. V. van Hooft; Herman S. Overkleeft; Gijsbert A. van der Marel; Jacques H. van Boom


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
31
Category
Article
ISSN
0931-7597

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Synthesis of Highly Functionalised Carbo
✍ Michiel A. Leeuwenburgh; Chantal C. M. Appeldoorn; Peter A. V. van Hooft; Herman 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 272 KB 👁 2 views

The synthesis of the ketoglycosidic enynes 5, 7 and 8 starting from 2,3,4,6-tetra-O-benzyl-D-glucopyranolactone ( 2) is described. These enynes are subjected to ruthenium-mediated