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ChemInform Abstract: Enantiospecific Total Synthesis of (+)- and (-)-Avarone and -Avarol.

✍ Scribed by E. P. LOCKE; S. M. HECHT

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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Stereoselective Synthesis of (+)-Avarol, (+)-Avarone, and Some Nonracemic Analogues. -The key step in the synthesis of the title compounds (VIII) and (IX) and the analogue (VII) is Li/NH3-mediated reduction of the enone (III) and subsequent trapping of the intermediate with the bromide (IV). The de