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ChemInform Abstract: Stereoselective Synthesis of (+)-Avarol, (+)-Avarone, and Some Nonracemic Analogues.

✍ Scribed by J. AN; D. F. WIEMER

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Stereoselective Synthesis of (+)-Avarol, (+)-Avarone, and Some Nonracemic Analogues.

-The key step in the synthesis of the title compounds (VIII) and (IX) and the analogue (VII) is Li/NH3-mediated reduction of the enone (III) and subsequent trapping of the intermediate with the bromide (IV). The derivative (XIV) is prepared via the ketone (XIII). -(AN,

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