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ChemInform Abstract: Enantiospecific Synthesis of Optically Active 6-Methoxytryptophan Derivatives and Total Synthesis of Tryprostatin A.

โœ Scribed by T. GAN; R. LIU; P. YU; S. ZHAO; J. M. COOK

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantiospecific Tot
ChemInform Abstract: Enantiospecific Total Synthesis of (+)-2-Pupukeanone.
โœ A. SRIKRISHNA; T. J. REDDY ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 37 KB

Enantiospecific Total Synthesis of (+)-2-Pupukeanone. -The first enantiospecific total synthesis of 2-pupukeanone (X) starting from readily available (R)-carvone (I) is described. Key step in the synthetic sequence is the construction of the tricyclic isotwistane carbon framework via 5-exo-trig rad