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ChemInform Abstract: Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis.

✍ Scribed by Hui-Wen Shih; Mark N. Vander Wal; Rebecca L. Grange; David W. C. MacMillan

Publisher
John Wiley and Sons
Year
2011
Weight
52 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The first enantioselective α‐benzylation of aldehydes with electron‐deficient aryl and heteroaryl substrates proceeds in the presence of a chiral imidazolidinone organocatalyst, an iridium photoredox catalyst, and in the presence of household fluorescent light.

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