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ChemInform Abstract: Enantioselective Synthesis of 2-Substituted-1,5-benzodiazepines Through Domino Reaction of o-Phenylenediamine and Chalcone Derivatives.

✍ Scribed by Xuan Fu; Juhua Feng; Zhenhua Dong; Lili Lin; Xiaohua Liu; Xiaoming Feng

Publisher: John Wiley and Sons
Year: 2012
Weight: 31 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201207175

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## 1,5-benzodiazepines / Cyclizations / Cycloadditions The reaction of o-phenylenediamine (4) with one, two or three equivalents of p-substituted 3-dimethylaminopropiophenone hydrochlorides 5a-e was studied. 4-Aryl-2,3-dihydro-1H-1,5-benzodiazepine derivatives 6a-e were obtained in good yields, alo

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