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ChemInform Abstract: Enantioselective Rhodium-Catalyzed Hydroboration of Olefins Using Chiral Bis(aminophosphine) Ligands.

✍ Scribed by Jean-Michel Brunel; Gerard Buono


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective Mo
✍ Frank Glorius; Andreas Pfaltz πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 2 views

Enantioselective Molybdenum-Catalyzed Allylic Alkylation Using Chiral Bisoxazoline Ligands. -The bisoxazolines shown in entry C) and D) are found to be good ligands in the enantioselective Mo-catalyzed allylic alkylation. With the acetate (Va) a branched/linear ratio of ΒΏ20:1 and an e.e. of 98% can