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ChemInform Abstract: Enantioselective Molybdenum-Catalyzed Allylic Alkylation Using Chiral Bisoxazoline Ligands.

✍ Scribed by Frank Glorius; Andreas Pfaltz

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199942071

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✦ Synopsis

Enantioselective Molybdenum-Catalyzed Allylic Alkylation Using Chiral Bisoxazoline Ligands.

-The bisoxazolines shown in entry C) and D) are found to be good ligands in the enantioselective Mo-catalyzed allylic alkylation. With the acetate (Va) a branched/linear ratio of ¿20:1 and an e.e. of 98% can be observed. -

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