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ChemInform Abstract: Iridium-Catalyzed Enantioselective Allylic Alkylation Using Chiral Phosphoramidite Ligand Bearing an Amide Moiety.

โœ Scribed by Gen Onodera; Keijiro Watabe; Masaki Matsubara; Kazuhiro Oda; Satoko Kezuka; Ryo Takeuchi


Publisher
John Wiley and Sons
Year
2009
Weight
35 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective Mo
โœ Frank Glorius; Andreas Pfaltz ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

Enantioselective Molybdenum-Catalyzed Allylic Alkylation Using Chiral Bisoxazoline Ligands. -The bisoxazolines shown in entry C) and D) are found to be good ligands in the enantioselective Mo-catalyzed allylic alkylation. With the acetate (Va) a branched/linear ratio of ยฟ20:1 and an e.e. of 98% can