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ChemInform Abstract: Enantioselective Reactions of Radicals at the α Position of γ-Lactams.

✍ Scribed by Ned A. Porter; Hao Feng; Ivanka K. Kavrakova

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

1999 stereochemistry stereochemistry (general, optical resolution) O

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Copper-Catalyzed Facile Carbon-Carbon Bond Forming Reactions at the α-Position of α,α,γ-Trichlorinated γ-Lactams. -Treatment of trichlorinated lactams of type (I) with olefins in the presence of CuCl/BIPY offers a simple way to introduce alkyl groups at the α-position of lactams. Sequential reaction