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ChemInform Abstract: Copper-Catalyzed Facile Carbon—Carbon Bond Forming Reactions at the α-Position of α,α,γ-Trichlorinated γ-Lactams.

✍ Scribed by Sho-ichi Iwamatsu; Hideo Kondo; Kouki Matsubara; Hideo Nagashima

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Copper-Catalyzed Facile Carbon-Carbon Bond Forming Reactions at the α-Position of α,α,γ-Trichlorinated γ-Lactams. -Treatment of trichlorinated lactams of type (I) with olefins in the presence of CuCl/BIPY offers a simple way to introduce alkyl groups at the α-position of lactams. Sequential reactions involving cyclization of N-allyl-trichloroacetamides and α-alkylation as well as intramolecular reactions are also possible. -(IWAMATSU, SHO-

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