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ChemInform Abstract: Enantioselective Alkynylation of Aldehydes Catalyzed by a Camphor Sulfonated Amino Alcohols Titanium(IV) Catalyst System.

✍ Scribed by Shaohua Gou; Zhongbin Ye; Zhiyu Huang; Xiping Ma

Publisher
John Wiley and Sons
Year
2010
Weight
21 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The complex generated in situ from optically active sulfonamide BCS and Ti(O‐iPr)~4~ is employed under optimized conditions for the synthesis of enantioenriched propargylic alcohols (up to 65% e.e.).

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