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ChemInform Abstract: Enantioselective Alkylation of Benzaldehyde with Diethylzinc Catalyzed by 1,1′- and 1,2-Disubstituted Ferrocenyl Amino Alcohols.

✍ Scribed by Stephanie Bastin; Francine Agbossou-Niedercorn; Jacques Brocard; Lydie Pelinski

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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## Abstract β‐Amino alcohols derived from (1__R__,2__S__)‐norephedrine were synthesized and used as ligands in the catalytic enantioselective diethylzinc addition to benzaldehydes. __N__‐alkylated (1__R__,2__S__)‐norephedrine‐based derivative 3a gave the highest enantioselectivity. The effects of d