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ChemInform Abstract: Enantioselective Addition of Diethylzinc to Benzaldehyde Catalyzed by Chiral Titanate Complexes with Helical Ligands.

✍ Scribed by C. GUO; J. QIU; X. ZHANG; D. VERDUGO; M. L. LARTER; R. CHRISTIE; P. KENNEY; P. J. WALSH


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Ethyl Nipecotate-Derived New Chiral Ligand. -In order to compare the chirality induction of chiral Ξ²-and Ξ³-amino alcohols, chiral Ξ³-amino alcohol DMM is synthesized and tested as catalyst in the addition of Et 2 Zn to various aldehyd