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ChemInform Abstract: Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Ethyl Nipecotate-Derived New Chiral Ligand.

✍ Scribed by So Ha Lee; Dai Sig Im; Chan Seong Cheong; Bong Young Chung

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Ethyl Nipecotate-Derived New Chiral Ligand. -In order to compare the chirality induction of chiral Ξ²-and Ξ³-amino alcohols, chiral Ξ³-amino alcohol DMM is synthesized and tested as catalyst in the addition of Et 2 Zn to various aldehydes. Alcohols (III) are obtained in moderate to good optical yields, but these e.e. values are lower than those afforded with chiral Ξ²-amino alcohols.

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