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ChemInform Abstract: Efficient Synthesis of 1,4-Thiazepin-3-one Derivatives and Their Ring Transformations.

โœ Scribed by B. ZALESKA; D. CIEZ; J. GROCHOWSKI; P. SERDA; W. WINNIK

Book ID
112037400
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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Efficient Synthesis of 1,4-Thiazepin-3-o
Efficient Synthesis of 1,4-Thiazepin-3-one Derivatives and Their Ring Transformations
โœ Zaleska, Barbara ;Cieลผ, Dariusz ;Grochowski, Jacek ;Serda, Pawel ;Winnik, Witold ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 535 KB

## Abstract A new oneโ€pot synthesis of title compounds 2 by reaction of ฮฒโ€aminothiocinnamic acid anilides 1 with ฮฑโ€haloacid halides is described. The ring of 1,4โ€thiazepine 2 in basic medium undergoes transformation to thiazolidinโ€4โ€ones 5.