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ChemInform Abstract: Efficient Cyclopropanation of C60 Starting from Malonates.

✍ Scribed by X. CAMPS; A. HIRSCH


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


The title reaction is achieved by direct treatment of C60 with malonates in the presence of CBr4 and DBU in good yields. By this significantly improved procedure monoadducts including chiral and sterically demanding dendritic side chains and also hexaadducts can be prepared. -(CAMPS, X.; HIRSCH,


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