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ChemInform Abstract: Cyclopropanation of C60 with Malonic Acid Mono-Esters.

✍ Scribed by J.-F. NIERENGARTEN; J.-F. NICOUD


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Efficient Cycloprop
✍ X. CAMPS; A. HIRSCH πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 25 KB πŸ‘ 1 views

The title reaction is achieved by direct treatment of C60 with malonates in the presence of CBr4 and DBU in good yields. By this significantly improved procedure monoadducts including chiral and sterically demanding dendritic side chains and also hexaadducts can be prepared. -(CAMPS, X.; HIRSCH,