ChemInform Abstract: Effective Oxidation of Alcohols by Iron(III)-Schiff Base-Triphenylphosphine Complexes.
β Scribed by Sandya Rani; Badekai Ramachandra Bhat
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 31 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The Ru[lll) Schiff base complex, 1 Ru[ L)CI,ICI; L = Gis[picolinaldehyde) o-phenylenediimine. catalyzes the oxidation of secondary alcohols by N-methylrnorpholine-N-oxide( NMO) or thal-Iium(lll) acetate as oxidant, Kinetic studies showed the formation of R u ( V ) species as the active intermediate
## Abstract A quadridentate Schiff base ligand of __N,Nβ²__βbis(2βhydroxyβ__Ξ±β__methylbenzylidene)ethylenediamine (HMBEDA) and its new iron(III) complex were synthesized and identified by analytical, spectral data (^1^H NMR, ^13^C NMR FTβIR and UVβvisible) and molar conductance. A rapid and efficie