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ChemInform Abstract: Dynamic Resolution of N-Boc-2-lithiopiperidine.

✍ Scribed by Iain Coldham; Sophie Raimbault; Praful T. Chovatia; Jignesh J. Patel; Daniele Leonori; Nadeem S. Sheikh; David T. E. Whittaker


Publisher
John Wiley and Sons
Year
2009
Weight
32 KB
Volume
40
Category
Article
ISSN
0931-7597

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## Abstract Proton abstraction of __N__‐__tert__‐butoxycarbonyl‐piperidine (__N__‐Boc‐piperidine) with __s__BuLi and TMEDA provides a racemic organolithium that can be resolved using a chiral ligand. The enantiomeric organolithiums can interconvert so that a dynamic resolution occurs. Two mechanism

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v