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ChemInform Abstract: Lithiation-Substitutions of N-Boc-N-Alkylcyclopropylamines.

✍ Scribed by Y. S. PARK; P. BEAK

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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Asymmetric Substitutions of 2-Lithiated
Asymmetric Substitutions of 2-Lithiated N-Boc-piperidine and N-Boc-azepine by Dynamic Resolution
✍ Iain Coldham; Sophie Raimbault; David T. E. Whittaker; Praful T. Chovatia; Danie 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 343 KB 👁 1 views

## Abstract Proton abstraction of __N__‐__tert__‐butoxycarbonyl‐piperidine (__N__‐Boc‐piperidine) with __s__BuLi and TMEDA provides a racemic organolithium that can be resolved using a chiral ligand. The enantiomeric organolithiums can interconvert so that a dynamic resolution occurs. Two mechanism