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ChemInform Abstract: Diphenylamine-Derived Bis-hydroxyamide Catalyzed Asymmetric Borane Reduction of Prochiral Ketones.

✍ Scribed by Jin Wang; Han Liu; Da-Ming Du

Publisher
John Wiley and Sons
Year
2009
Weight
25 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

πŸ“œ SIMILAR VOLUMES

Catalytic asymmetric borane reduction of
Catalytic asymmetric borane reduction of prochiral ketones using chiral camphor-derived mercapto-alcohols
✍ Zhou Yong-Gui; Hou Xue-Long; Dai Li-Xin πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 264 KB

Easily available D-(+)-camphor-derived chiral mercapt\*alcohols 2 and 3 were employed for catalytic asymmetric borane reduction of aromatic ketones. Moderate enantioselectivities with e.e. 20.2-72.1% were obtained with 10 mol% catalyst. Opposite asymmetric induction was achieved' when mercaptc-alcoh