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Asymmetric Borane Reduction of Prochiral Ketones Catalyzed by Phosphinamides Prepared from L-Serine.

✍ Scribed by Kang-Ying Li; Zheng-Hong Zhou; Li-Xin Wang; Guo-Feng Zhao; Michael C. K. Choi; Qi-Lin Zhou; Chu-Chi Tang

Publisher
John Wiley and Sons
Year
2003
Weight
92 KB
Volume
34
Category
Article
ISSN
0931-7597

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A Novel Phosphinamide Catalyst for the Asymmetric Reduction of Ketones by Borane. -The novel phosphinamide ("cat.") is a readily available, robust, versatile and recoverable reagent for the catalytic asymmetric reduction of ketones by borane. -(GAMBLE, M.