Highly Enantioselective Reduction of Prochiral Ketones with N,N-Diethylaniline • borane (DEANB) in Oxazaborolidine-Catalyzed Reductions. -A variety of prochiral ketones (I) is enantioselectively reduced to the corresponding alcohols (II) using diethylaniline borane in the presence of a chiral oxazab
Asymmetric Oxazaborolidine-Catalyzed Reduction of Prochiral Ketones with N-tert-Butyl-N-trimethylsilylamine—borane.
✍ Scribed by Ramon E. Huertas; Joseph A. Corella; John A. Soderquist
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 101 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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An Optimized in situ Procedure for the Oxazaborolidine Catalyzed Enantioselective Reduction of Prochiral Ketones. -The catalyst prepared from (S)-diphenyl prolinol is found to be the best amongst several other analogues for the reduction of alkyl aryl ketones. -(PRASAD, K. R.