Highly Enantioselective Reduction of Prochiral Ketones with N,N-Diethylaniline โข borane (DEANB) in Oxazaborolidine-Catalyzed Reductions. -A variety of prochiral ketones (I) is enantioselectively reduced to the corresponding alcohols (II) using diethylaniline borane in the presence of a chiral oxazab
โฆ LIBER โฆ
ChemInform Abstract: An Optimized in situ Procedure for the Oxazaborolidine Catalyzed Enantioselective Reduction of Prochiral Ketones.
โ Scribed by K. R. K. PRASAD; N. N. JOSHI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
An Optimized in situ Procedure for the Oxazaborolidine Catalyzed Enantioselective Reduction of Prochiral Ketones.
-The catalyst prepared from (S)-diphenyl prolinol is found to be the best amongst several other analogues for the reduction of alkyl aryl ketones. -(PRASAD, K. R.
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