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ChemInform Abstract: Diastereoselective Triple Radical Cyclization of a Bromomethyldimethylsilyl Allyl Ether.

✍ Scribed by A. S. KENDE; M. JOURNET; R. G. BALL; N. N. TSOU


Book ID
112040953
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Regio-and Stereospecificity in Radical Cascade Cyclizations of TMS-Alcyne Containing Allyl Bromomethyldimethylsilyl Ethers. -Tandem radical cyclization of the racemic (E)-silane (I) yields the all-cis substituted vinylcyclopentanol (II) as an isoprostanoid precursor together with minor amounts of t

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